페놀과 알코올의 비교, 에테르(Ether)의 물리적 성질

목차

1.알코올과 페놀의 비교

2.에테르(Ether)의 물리적 성질

본문내용

on the relative sizes of the crown ether and the cation and the number of binding sites around the cation. L. G. Wade, Jr., 『ORGANIC CHEMISTRY third edition』, whitman college, 2006, p.597-598.
Complexation by crown ethers often allows polar inorganic salts to dissolve in nonpolar organic solvents. This enhanced solubility allows polar salts to be used under aprotic condition, where the uncomplexed anions may have greatly enhanced reactivity. For example, in Section 6-10A we used 18-crown-6 to dissolve potassium fluoride in acetonitrile (CH3CN), where the poorly solvated fluoride ion is a moderately strong nucleophile. Many other salts, including carboxylate salts (RCOO-K+), cyanides (KCN), and permanganates (KMnO4), can be dissolved in aprotic (and often nonpolar) organic solvents using crown ethers. In each, the crown ether complexes only the cation, leaving the anion bare and highly reactive. L. G. Wade, Jr., 『ORGANIC CHEMISTRY third edition』, whitman college, 2006, p.598.
참고문헌
hartcrainehart, 채우기 외 4인『ORGANIC CHEMISTRY eleventh edition』, 교보문고, 2005.
주정희, 『ORGANIC CHEMISTRY third edition』, 자유아카데미, 2006.
L. G. Wade, Jr., 『ORGANIC CHEMISTRY third edition』, whitman college, 2006.

키워드

알코올과 페놀,   알코올,   페놀,   에테르,   ether,   에테르의 물리적성질